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Description 

一、present

In industrial hydrogen purification by pressure swing adsorption (PSA), the adsorbents generally adsorb the easily adsorbed components out of the gas mixture at ambient temperature and high pressure, while the not easily adsorbed components (such as hydrogen) flow out from one end of the bed as the product, and then the adsorbent bed is depressurized to desorb the adsorbates and discharge them out from the other end of the bed, thus gas separation and purification is realized, and the adsorbents are regenerated at the meantime.However, in general PSA process, there are two ways to regenerate the adsorbents, one is to "purge" the bed with product gas to reduce the partial pressure of the adsorbed impurities and displace the desorbed impurities. The advantage is that it can be operated under normal pressure, but the disadvantage is that more product gas is lost; Another regeneration method is using vacuum, desorbing the adsorbed impurities under negative pressure, which is commonly known as vacuum pressure swing adsorption (VPSA or VSA). The advantage of VPSA process is high product yield, but the disadvantage is that a vacuum pump is required, and the energy consumption of the unit is relatively higher. In practice, which method of the above to use depends on feed gas composition, product purity and yield requirements, etc.

二、Technical features 

1.Simple, advanced and reliable process flow with strong applicability of feed gases;

2.High hydrogen product purity, from 98% to 99.999%;

3.High hydrogen recovery, from 60% to 99% depending on gas source and product conditions; 

4.Wide operating pressure range of 0.2-7.0MPaG, low energy consumption, high flexibility of 20-120%, and continuous on-stream time over 4 years;

5.High degree of automation, with functions such as self-adaptive adjustment and automatic fault diagnosis, easy startup and shutdown, and unmanned automatic control.

三、Applications

變換氣,甲醇裂解氣,甲醇馳放氣、合成氨尾氣,煉廠加氫低分氣、焦?fàn)t煤氣、水煤氣、催化干氣,重整氫等各類含氫氣體。


Flow Schematic

 


Cases

listCustomer  
Scale
Raw gas
Purity
Process Route
Typical




1中石化四川維尼綸廠7000Nm3/hMethanol off-gas
99.9%PSA(It's been in operation for 20 years and has been certified by Sinopec.)
2蘇丹喀土穆煉油廠11000Nm3/hFCC dry gas
99.9%VPSA(China's largest export hydrogen plant)
3AIR PRODUCT2000Nm3/hSyngas
99.9%PSA(3.5MPa(G))
4中石化南京化學(xué)工業(yè)公司(2套)63000Nm3/hFertiliser syngas
99.9%VPSA(4.0MPa(G))
5中石化福建煉化公司80000Nm3/hPOX tail gas
99.9%PSA(4.5MPa(G))
6大唐電力化工公司10000Nm3/hMethanol off-gas
99.9%PSA(5.0MPa(G))
Reformulated PSA Typical Performance




1中海油惠州煉化公司二期120000Nm3/hReforming gas+Low fraction gas99.90%PSA
2中國石油獨(dú)山子石化分公司140000Nm3/hReforming gas
99.90%PSA
3中國石化湛江東興石油化工有限公司100000Nm3/hReforming gas
99.90%PSA
4廈門騰龍芳烴有限公司200000Nm3/hReforming gas
99.90%PSA
Typical performance of coal-to-hydrogen PSA




1中海油惠州煉化公司二期200000Nm3/hPOXSyngas99.90%PSA
2寧波中金石化有限公司108000Nm3/hSyngas+Low-content gas99.90%一段VPSA+二段PSA
3中國石化湛江東興石油化工有限公司2*90000Nm3/hSyngas
99.90%PSA
Typical performance of tail gas PSA recovery




1中國石化北海煉化有限責(zé)任公司32000 Nm3/hRefinery dry gas
99.90%VPSA
2中國石油錦西石化分公司22000 Nm3/hHydrogen-containing gases
99.90%VPSA
3中國石化海南煉油化工有限公司20000 Nm3/hRefinery dry gas
99.90%VPSA
Typical performance of PSA for transformed gas




1中石油大連石化公司2×100000Nm3/hConversion gas
99.90%PSA
2中國石化股份有限公司武漢分公司80000Nm3/hConversion gas
99.90%PSA
3中石化股份有限公司天津分公司100000Nm3/hConversion gas
99.90%PSA
Typical Performance of Coke Oven Gas PSA




1河南金江煉化有限責(zé)任公司33000 Nm3/hCoke oven gas
99.90%TSA+PSA
2寶鋼廣東湛江鋼鐵基地項(xiàng)目2600 Nm3/hCoke oven gas
99.999%TSA+PSA
VPSA-CO2



1遼寧華錦通達(dá)化工股份有限公司煉化分公司20000 Nm3/hHydrogen PSA tail gas
95%VPSA
2寧波中金石化有限公司108000Nm3/hSyngas
99.90%一段VPSA
C2+Recycling Projects



1黑龍江省龍油石油化工股份有限公司40000 Nm3/hCatalytic dry gas
C2+VPSA
Pressure change adsorption EPC project




1內(nèi)蒙古伊泰化工有限責(zé)任公司49000 Nm3/h;27000 Nm3/hPermeate gas;Purification gas99.90%PSA
2黑龍江省龍油石油化工股份有限公司80000 Nm3/h;30000 Nm3/hConversion gas;Low-content gas99.90%PSA
3黑龍江省龍油石油化工股份有限公司40000 Nm3/hCatalytic dry gas
C2+VPSA
4廈門騰龍芳烴有限公司200000Nm3/hReformulated gas
99.90%PSA

Hydrogen purification by PSA

In industrial hydrogen purification by pressure swing adsorption (PSA), the adsorbents generally adsorb the easily adsorbed components out of the gas ...
Hydrogen purification by PSA
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