Description
一、present
In industrial hydrogen purification by pressure swing adsorption (PSA), the adsorbents generally adsorb the easily adsorbed components out of the gas mixture at ambient temperature and high pressure, while the not easily adsorbed components (such as hydrogen) flow out from one end of the bed as the product, and then the adsorbent bed is depressurized to desorb the adsorbates and discharge them out from the other end of the bed, thus gas separation and purification is realized, and the adsorbents are regenerated at the meantime.However, in general PSA process, there are two ways to regenerate the adsorbents, one is to "purge" the bed with product gas to reduce the partial pressure of the adsorbed impurities and displace the desorbed impurities. The advantage is that it can be operated under normal pressure, but the disadvantage is that more product gas is lost; Another regeneration method is using vacuum, desorbing the adsorbed impurities under negative pressure, which is commonly known as vacuum pressure swing adsorption (VPSA or VSA). The advantage of VPSA process is high product yield, but the disadvantage is that a vacuum pump is required, and the energy consumption of the unit is relatively higher. In practice, which method of the above to use depends on feed gas composition, product purity and yield requirements, etc.
二、Technical features
1.Simple, advanced and reliable process flow with strong applicability of feed gases;
2.High hydrogen product purity, from 98% to 99.999%;
3.High hydrogen recovery, from 60% to 99% depending on gas source and product conditions;
4.Wide operating pressure range of 0.2-7.0MPaG, low energy consumption, high flexibility of 20-120%, and continuous on-stream time over 4 years;
5.High degree of automation, with functions such as self-adaptive adjustment and automatic fault diagnosis, easy startup and shutdown, and unmanned automatic control.
三、Applications
變換氣,甲醇裂解氣,甲醇馳放氣、合成氨尾氣,煉廠加氫低分氣、焦?fàn)t煤氣、水煤氣、催化干氣,重整氫等各類含氫氣體。
Flow Schematic
Cases
list | Customer | Scale | Raw gas | Purity | Process Route |
一 | Typical | ||||
1 | 中石化四川維尼綸廠 | 7000Nm3/h | Methanol off-gas | 99.9% | PSA(It's been in operation for 20 years and has been certified by Sinopec.) |
2 | 蘇丹喀土穆煉油廠 | 11000Nm3/h | FCC dry gas | 99.9% | VPSA(China's largest export hydrogen plant) |
3 | AIR PRODUCT | 2000Nm3/h | Syngas | 99.9% | PSA(3.5MPa(G)) |
4 | 中石化南京化學(xué)工業(yè)公司(2套) | 63000Nm3/h | Fertiliser syngas | 99.9% | VPSA(4.0MPa(G)) |
5 | 中石化福建煉化公司 | 80000Nm3/h | POX tail gas | 99.9% | PSA(4.5MPa(G)) |
6 | 大唐電力化工公司 | 10000Nm3/h | Methanol off-gas | 99.9% | PSA(5.0MPa(G)) |
二 | Reformulated PSA Typical Performance | ||||
1 | 中海油惠州煉化公司二期 | 120000Nm3/h | Reforming gas+Low fraction gas | 99.90% | PSA |
2 | 中國石油獨(dú)山子石化分公司 | 140000Nm3/h | Reforming gas | 99.90% | PSA |
3 | 中國石化湛江東興石油化工有限公司 | 100000Nm3/h | Reforming gas | 99.90% | PSA |
4 | 廈門騰龍芳烴有限公司 | 200000Nm3/h | Reforming gas | 99.90% | PSA |
三 | Typical performance of coal-to-hydrogen PSA | ||||
1 | 中海油惠州煉化公司二期 | 200000Nm3/h | POXSyngas | 99.90% | PSA |
2 | 寧波中金石化有限公司 | 108000Nm3/h | Syngas+Low-content gas | 99.90% | 一段VPSA+二段PSA |
3 | 中國石化湛江東興石油化工有限公司 | 2*90000Nm3/h | Syngas | 99.90% | PSA |
四 | Typical performance of tail gas PSA recovery | ||||
1 | 中國石化北海煉化有限責(zé)任公司 | 32000 Nm3/h | Refinery dry gas | 99.90% | VPSA |
2 | 中國石油錦西石化分公司 | 22000 Nm3/h | Hydrogen-containing gases | 99.90% | VPSA |
3 | 中國石化海南煉油化工有限公司 | 20000 Nm3/h | Refinery dry gas | 99.90% | VPSA |
五 | Typical performance of PSA for transformed gas | ||||
1 | 中石油大連石化公司 | 2×100000Nm3/h | Conversion gas | 99.90% | PSA |
2 | 中國石化股份有限公司武漢分公司 | 80000Nm3/h | Conversion gas | 99.90% | PSA |
3 | 中石化股份有限公司天津分公司 | 100000Nm3/h | Conversion gas | 99.90% | PSA |
六 | Typical Performance of Coke Oven Gas PSA | ||||
1 | 河南金江煉化有限責(zé)任公司 | 33000 Nm3/h | Coke oven gas | 99.90% | TSA+PSA |
2 | 寶鋼廣東湛江鋼鐵基地項(xiàng)目 | 2600 Nm3/h | Coke oven gas | 99.999% | TSA+PSA |
七 | VPSA-CO2 | ||||
1 | 遼寧華錦通達(dá)化工股份有限公司煉化分公司 | 20000 Nm3/h | Hydrogen PSA tail gas | 95% | VPSA |
2 | 寧波中金石化有限公司 | 108000Nm3/h | Syngas | 99.90% | 一段VPSA |
八 | C2+Recycling Projects | ||||
1 | 黑龍江省龍油石油化工股份有限公司 | 40000 Nm3/h | Catalytic dry gas | C2+ | VPSA |
九 | Pressure change adsorption EPC project | ||||
1 | 內(nèi)蒙古伊泰化工有限責(zé)任公司 | 49000 Nm3/h;27000 Nm3/h | Permeate gas;Purification gas | 99.90% | PSA |
2 | 黑龍江省龍油石油化工股份有限公司 | 80000 Nm3/h;30000 Nm3/h | Conversion gas;Low-content gas | 99.90% | PSA |
3 | 黑龍江省龍油石油化工股份有限公司 | 40000 Nm3/h | Catalytic dry gas | C2+ | VPSA |
4 | 廈門騰龍芳烴有限公司 | 200000Nm3/h | Reformulated gas | 99.90% | PSA |